57A114
Formation of brine pockets in sea ice
Bernd Kutschan, Klaus Morawetz, Sibylle Gemming, Silke Thoms,
Augusto F. Oliveira
Corresponding author: Bernd Kutschan –
kutschan@gmx.de
Brine channels are formed in sea ice under certain
constraints and represent a habitat of different microorganisms. The complex
system depends on a number of various quantities as salinity, density, pH value
or temperature. Each quantity influences the process of brine-channel formation.
We develop a suitable phenomenological model for the formation of brine channels
both referring to the Ginzburg-Landau theory of phase transitions as well as to
the chemical basis of morphogenesis according to Turing. We construct a Turing
space in which a structure formation is possible and conclude from the critical
wave number on the size of the structure and the critical parameters. The
theoretically deduced transition rates have the same magnitude as the
experimental values. The model creates channels of similar size as observed
experimentally. An extension of the model towards channels with different sizes
is possible. Microscopic insights into the brine-channel formation in sea ice
can be achieved by ‘ab initio’ calculations with the help of
molecular dynamics simulations. If we place halide ions in water we hope to find
the onset of a brine-channel formation and to determine the minimal size of
brine pockets.
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